Slurry components in metal chemical mechanical planarization cmp process. However, it is limited to find the optimum conditions for the slurry by only experimental approaches. Chemical mechanical polishing, cabot microelectronics. A wide variety of chemical mechanical polishing options are available to you, such as stainless steel. The polishing was carried out using the commercial slurry procured from cabot microelectronics inc.
Analysis of slurry flow in chemical mechanical polishing by krzysztof d. The nanoceria composition for chemical mechanical polishing according to an embodiment of the present invention can ensure high dispersibility of abrasive grains in a slurry composition even without a separate dispersion aid and can improve the removal rate of the conventional slurry slurry for cmp, the degree of roughness of the wafer is improved and the influence on the scratch of the wafer can be effectively suppressed. A novel approach of chemical mechanical polishing using. Osseoasare department of materials science and engineering the pennsylvania state university. Chemical mechanical planarization cabot microelectronics. Study of conditioner abrasives and synthesis of nanozirconia for potential slurry applications by chhavi manocha a thesis submitted in partial fulfillment of the. During conventional polishing, both the rotation rates of polishing pads and mct wafers were 40 rpm. Chemical mechanical polishing includes traditional polishing, eg. The new process was faster than the previous silica based polishing method and. Chemical mechanical polishing slurry for amorphous ge2sb2te5 zhitang song1,2, weili liu1,2, liangyong wang1,2 1shanghai institute of. Chemical mechanical planarization of electronic materials.
Slurry chemical mechanical polishing cmp semiconductor analysis. Us6251150b1 slurry composition and method of chemical. Effect of slurry composition on the chemical mechanical. There are 1,717 suppliers who sells chemical mechanical polishing on, mainly located in asia. The slurries can be hand sprayed onto the lapping polishing platen or applied by an electronic dispensing system to control cost and reduce waste. The solid lines are model predictions using surface layer thickness t as the fitting.
Cmp chemical mechanical planarization customers just starting in cmp or considering implementing the process find substantial benefits from utilizing entrepix cmp fast forward services. The effect of slurry composition and wafer flatness on a material removal rate mrr and resulting surface roughness which are evaluation parameters to determine the cmp characteristics of the onaxis 6hsic substrate were systematically investigated. This phase stops at the surface of the barrier layer. Chemicalmechanical polishing slurry formulation and method for tungsten and. A wide variety of chemical mechanical polishing options are available. Slurry chemistry effects on copper chemical mechanical. Figure 2 shows the optical images of surface morphologies after fixedabrasive lapping by alumina with a size of 5. Pdf slurry components in metal chemical mechanical. Shelf life can be an important consideration for readymade slurries and. Study of conditioner abrasives and synthesis of nanozirconia for potential slurry applications by chhavi manocha a thesis submitted in partial fulfillment of the requirements for the degree of master of chemical engineering department of chemical and biomedical engineering college of engineering. Analysis of slurry flow in chemicalmechanical polishing by krzysztof d. Chemical mechanical planarization cmp is a wet polishing technique employed to smooth the surface of various materials using a combination of chemical and mechanical forces to achieve finer and longer lines on semiconductor devices. Cmp is a surface polishing and material removal process involving both chemical attack and abrasive removal. Four controllable factors of the zircon flour and fusedsilica powder based slurries were studied at three levels each by taguchis parametric approach and singleresponse optimization of plate weight was conducted to identify.
Us patent for chemical mechanical planarization slurry composition. Ee143 f2010 lecture 17 university of california, berkeley. Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove unwanted conductive or dielectric materials on the silicon wafer, achieving a nearperfect flat and smooth surface upon which layers of integrated circuitry are built. Cmp technological paradigm shift to surface cleaning.
Cerium oxide slurries in chemical mechanical polishing. Microelectronic applications of chemical mechanical planarization edited by yuzhuo li. Experimental and numerical analysis of an inhibitor. Electrochemical behavior of aluminum during chemical mechanical polishing in phosphoric acid base slurry hongshi kuo and wenta tsai department of materials science and engineering, national cheng kung university, tainan, taiwan the electrochemical behavior of aluminum in chemical mechanical polishing cmp slurry was investigated using. This invention is also a chemical mechanical polishing slurry and composition that has a long shelf life. This paper deals with the study of the effect of primary slurry parameters on the plate weight ceramic retention test in ceramic shell investment casting process. Polishing pressure as well as the flow rate of the polishing slurry and rotation of the polishing pad determine the fluidynamics of the polishing process. Disclosed is a method of chemmech polishing an electronic component substrate. Triboelectrochemical investigation of a slurry composition to reduce dissolution and galvanic corrosion during chemical mechanical planarization of curu interconnects. The mechanism of low ph silica based oxide slurries. Furthermore, the cmp composition of the invention should have a long shelf life.
The polishing was carried out using the commercial slurry procured from cabot. Pdf chemical mechanical polishing slurry of copper usually contains more than four compositions, in which strong acids, alkalis or hazardous. Chemical mechanical polishing cmp is a finishing process that is used to prepare substrates for electronic devices. It has been found that such a slurry produces a high material removal rate for barium strontium titanate bst polishing, without damage to the surface of the bst workpiece commonly found with other slurry compositions. Chemical mechanical planarization cmp slurries are liquid dispersions containing active chemicals and microabrasive grains used for chemical mechanical planarization. Chemical mechanical polishing slurry for amorphous. Beijing university of aeronautics and astronautics, 1994 a thesis submitted in partial fulfillment of. Chemical mechanical polishing planarization cmp is a critical step in semiconductor manufacturing. From table 1, it can be found that among all contact area values for the polishing slurry compositions of comparative examples 11 and 12 and examples 11 to 16, the polishing slurry. Cmp is a standard manufacturing process practiced at the semiconductor industry to fabricate integrated circuits and memory disks.
Effect of applied potential on the chemical mechanical. Chemical mechanical polishing cmp is the planarization method that has been selected by the. December 14, 2011 the dow chemical company page 5 of 7 other for slurries containing silica abrasives, there is. Abrasive effects in oxide chemical mechanical polishing mrs. Us4954142a method of chemicalmechanical polishing an.
A chemical mechanical polishing slurry is used to wet the polishing surface 26 and contains an abrasive to facilitate mechanical polishing of the integrated circuit structure 10. Analysis of slurry flow in chemicalmechanical polishing. Chemical mechanical polishing slurry for amorphous ge 2. The goal of the 1st phase cmp is to remove copper layer with high efficiency. Chemical mechanical polishing, cabot microelectronics cmp. Chemical mechanical polishing of copper using nanoparticle. Chemicalmechanical polishing of lowdielectricconstant. Slurry chemical mechanical polishing cmp semiconductor. The slurry composition for chemical mechanical polishing of metal layer on semiconductor substrates, comprising hydrogen peroxide, nitric acid, malic acid, a silica abrasive in an amount exceeding 8 wt %, a fepropylenediaminetetraacetate fepdta complex and deionized water. Chemical mechanical planarization cmp slurries selection guide. As the amount of organic content in sog increases, the chemicalmechanical polishing cmp removal rate. The lapmaster range of diamond slurries has been formulated for use on many different types of lapping plates and polishing pads. Slurry components in metal chemical mechanical planarization. White, lamon jones and richard romine cabot microelectronic corp.
Polishing with slurry a cleaner polishing with slurry b cleaner. Effect of slurry composition on plate weight in ceramic. Effect of slurry composition on the chemical mechanical polishing of thin diamond films. The cmp slurry composition is an important factor because additives in the slurry generally improve the polishing performance. Removal rate shelf life silicon nitride fumed silica settling rate. Lastly, cmp behavior of copper wafer was examined under different polishing conditions. Wo2016024177a1 chemicalmechanical polishing composition. In order to avoid the environmental pollution and the harm to body of traditional polishing slurries, an environmentfriendly chemical mechanical polishing technology is proposed for sic wafer in this. Aurora, il 60504 abstract the mechanism of oxide polishing at low ph in the presence of an organic cation is discussed. Wo1998042791a1 chemicalmechanical polishing slurry. Another aspect of this invention is a chemical mechanical. Chemical mechanical planarization slurry composition comprising. Effect of slurry composition on plate weight in ceramic shell. Figure 4 further shows the particle size of acidic slurry and alkaline slurry as a function of collection time during polishing of gst.
The effect of slurry composition and flatness on subsurface. Science and technology of advanced materials 2017, 18 1, 654663. Effect of slurry composition on the chemical mechanical polishing of. The cmp slurry composition is an important factor because. To achieve a scratchfree planar surface, the slurry chemistry needs to be adjusted so that the polishing rate is balanced between the chemical and. Wo1998023408a1 a composition and slurry useful for metal cmp. Chemicalmechanical polishing cmp is often associated with chemicalmechanical planarization which is a polishing process assisted by chemical reactions to remove surface materials. Specifically designed for optimal polishing performance on cplane sapphire, saintgobains 9221 nano alumina slurry offers a slight modification to the crystal structure. New to cmp cmp chemical mechanical planarization customers just starting in cmp or considering implementing the process find substantial benefits from utilizing entrepix cmp fast forward. The chemical mechanical polishing process is continued until the structure 10 is effectively planarized. Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper removal process. Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove. Chemical mechanical planarization for microelectronics applications. Welcome to the most trusted and comprehensive semiconductor analysis.
Cmp processes, tools and slurries utilize composite particles that include core. Effect of slurry composition on the chemical mechanical polishing of thin diamond films jessica m. Nov 07, 2000 a chemical mechanical polishing slurry is used to wet the polishing surface 26 and contains an abrasive to facilitate mechanical polishing of the integrated circuit structure 10. Chemicalmechanical planarization cmp slurries created. Polycrystalline alumina polishing slurries products. Jan 26, 2017 from table 1, it can be found that among all contact area values for the polishing slurry compositions of comparative examples 11 and 12 and examples 11 to 16, the polishing slurry compositions of examples to 16 in which three types of silica abrasive particles were mixed have relatively high contact area values, and the polishing slurry compositions of examples 11 and 12 in which. Slurry cmp resources are compiled in this industrial portal which provides information on manufacturers, distributors and service companies in the semiconductor analysis. Chemical mechanical polishing and cleaning cleaning paradigm need to be shifted. The molecular structure and film properties of both polymers were characterized by their fourier transform infrared spectra, refractive indices, dielectric constants, and atomic force microscopy. Chemical mechanical polishing composition and method of. Osseoasare department of materials science and engineering the pennsylvania state university university park, pa 16802 cerium oxide, ceria ceo2, has been widely used as an abrasive in glass polishing and in semiconductor fabrication. In this study, the film properties and chemical mechanical polishing cmp characteristics of the low dielectric constant polymers hydridoorgano siloxane and methyl silsesquioxane are presented. Chemicalmechanical planarization of semiconductor materials pp 215249 cite as. The present invention provides a slurry composition for chemical mechanical polishing comprising spinel particles having the formula aoxz 2 o 3 wherein a is at least one divalent cation, z is at least one trivalent cation, and 0.
A dynamic measurement of the slurry properties coupled. Kopanski submitted to the department of mechanical engineering on may 23, 2005 in partial fulfillment of the requirements for. In conventional polishing, free abrasives of alumina were used with size of 1. Ee143 f2010 lecture 17 wafer is polished using a slurry containing silica abrasives 1090 nm particle size etching agents e. The copper wafers were characterized by afm in order to analyze surface roughness. Described are a chemicalmechanical polishing cmp composition. Effects of slurry formulations on chemicalmechanical. A slurry composition for chemical mechanical polishing cmp of a phasechange memory device is provided. The slurry flow controls the supply and the exchange of chemical compounds at the silicon surface and the removal of the reaction products. Cmp technological paradigm shift to surface cleaning hong jin kim. Pdf environment friendly chemical mechanical polishing of copper. In order to make the polishing slurry distribution more uniform over the polishing region, a new kind of polishing pad, which has sunflower seed pattern, has been designed based on the. Phosphoric acid base slurry containing alumina powders was prepared.
Nanocrystalline diamond ncd thin films grown by chemical vapour deposition have an intrinsic surface roughness, which hinders the. A dynamic measurement of the slurry properties coupled with defined control limits can be used to determine a slurry health. The composition of cmp slurry wastewaters is described, along with the. Environmentfriendly chemical mechanical polishing slurry. Chemical mechanical planarization cmp slurries are liquid dispersions. Chemical mechanical polishing or planarization is a process of smoothing surfaces with the combination of chemical and mechanical forces. The slurries can be hand sprayed onto the lappingpolishing platen or. A cupric salt cmp slurry was employed to improve the throughput and surface finish on a conventional polishing machine. Electrochemical behavior of aluminum during chemical.
The slurry was tailored later to reduce defects and surface nonplanarity introduced by the. The electrochemical behavior of aluminum in chemical. One disclosed composition comprises 85% water, 4% nacl, 4% h 2 o 2, and 7% colloidal silica. The new process was faster than the previous silica based polishing method and resulted in a mirrorlike surface blake and mendel, 1970. Control of nanomaterials used in chemical mechanical. The transformation in electronic devices that has occurred in the past few decades has relied greatly on the efficiency and effectiveness of planarization using slurry polishing. The polishing slurry provides the mean s by which both chemical and mechanical tribological actions are used to remove and subsequently planarize the wafer surface.
Solgel silica particles with very narrow size distributions were used for preparing the polishing slurries. Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper. The mechanism of low ph silica based oxide slurries michael l. It can be thought of as a hybrid of chemical etching and free abrasive polishing. The slurry temperature was controlled at 25 6 28c during static and polishing state tests. The concept of chemical mechanical planarization cmp was.
In this study, we have characterized the effects of abrasive properties, primarily particle size, on the chemical mechanical polishing cmp of oxide films. Electrochemical analysis of the slurry composition for. Chemical mechanical planarization cmp slurries selection. Kopanski submitted to the department of mechanical engineering on may 23, 2005 in partial fulfillment of the requirements for the degree of master of science in mechanical engineering abstract chemical mechanical polishing cmp is one of the enabling processes used in. Chemical mechanical polishing slurry for amorphous ge2sb2te5.
Slurry chemical mechanical planarization cmp slurries. A typical cmp process mainly consists of th ree components. But the dependence of kp on process variables like slurry composition and pad. Dielectric chemical mechanical polishing cmp was implemented in semiconductor. The process uses an abrasive and corrosive chemical slurry commonly a colloid in conjunction with a polishing pad and retaining ring, typically of a greater diameter than the wafer. In this study, the film properties and chemicalmechanical polishing cmp characteristics of the low dielectric constant polymers hydridoorgano siloxane and methyl silsesquioxane are presented. Slurry containing mainly pure water, a chemical reagent and different polishing particles are used between the polishing pad and the wafer. Abrasive effects in oxide chemical mechanical polishing.
Three mct wafers were distributed on the periphery of a circular plate of aluminium alloy in diameter of 150 mm. Nanomaterials nm of silica sio 2, cerium ceo 2, and alumina al 2 o 3 are used in liquid slurries by a number of industrial applications, including chemical mechanical polishingplanarization cmp. The effect of slurry composition and flatness on sub. Both for the slurries at ph2 and ph11, the mean particle size is around 65nm with a variation within f3nm. An improved slurry composition and method of polishing a workpiece are disclosed. Mrr 220 nmmin with 2 wt% h2o2 mrr prediction and particle size for alumina with cu slurry additives mrr 110 nmmin particle size 0. The composition of the slurry was 5 vol % h3po4 1 0. This composition allows use of a neutral ph slurry for chemicalmechanical polishing many surfaces. The effect of slurry composition and wafer flatness on a material removal rate mrr and resulting surface roughness which are evaluation parameters to determine the cmp characteristics of the on. Kr1016359b1 nano ceria slurry composition for chemical. The composition of the test slurry is shown in table ii. Our team of industryexperienced cmp professionals brings its knowledge to bear on every customer interaction to complete yield analysis on first.
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